Table
1 – Approximate correlation between molecular size and effective zeolite molecular
sieve aperture (ref 2, 94)
|
Approx Size (ang) |
Example |
Window(no. of oxygens) |
Molecules Accepted |
|
<3.8 |
CaM, BaM |
8, 12 |
He, Arm CO, H2O2,
N2, NH3, H2O |
|
<4.0 |
NaM, NaA |
8 |
Kr, CH4, C2H6,
CH3OH, CH3Cl, CO2, C2H2,
CS2 |
|
<4.9 |
CaA, CaC |
8 |
C3H8, n-C4H10,
C2H5Cl, CH5OH, C2H5NH2,
CHF2Cl, CHF3, CH3I, B2H6 |
|
<7.8 |
NaX |
12 |
SF6, C4H10,
C5H12, CHCl3, (CH3)2CHOH,
n-C3F8, B5H9, CCl4,
C2F2Cl4, C6H6, C6H5CH3,
cyclopentane, cyclohexane, pyridine, dioxane, naphthalene, quionline |
|
<10 |
CaX |
12 |
1,3,5-Triethylbenzene |