Table 1 – Approximate correlation between molecular size and effective zeolite molecular sieve aperture (ref 2, 94)

Approx Size (ang)

Example

Window(no. of oxygens)

Molecules Accepted

<3.8

CaM, BaM

8, 12

He, Arm CO, H2O2, N2, NH3, H2O

<4.0

NaM, NaA

8

Kr, CH4, C2H6, CH3OH, CH3Cl, CO2, C2H2, CS2

<4.9

CaA, CaC

8

C3H8, n-C4H10, C2H5Cl, CH5OH, C2H5NH2, CHF2Cl, CHF3, CH3I, B2H6

<7.8

NaX

12

SF6, C4H10, C5H12, CHCl3, (CH3)2CHOH, n-C3F8, B5H9, CCl4, C2F2Cl4, C6H6, C6H5CH3, cyclopentane, cyclohexane, pyridine, dioxane, naphthalene, quionline

<10

CaX

12

1,3,5-Triethylbenzene

 

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