University of Vermont

CHEM 201: Advanced Chemistry Laboratory

Chem 201 Lab 3: NMR

Lab 3: High Resolution NMR

Equipment:

Chem Dept Agilent (Varian) 500 MHz NMR with VnmrJ software

Handouts & References:

get PDFs in red

  • D.P. Shoemaker, C.W. Garland, & J.W. Nibler, Expt 44: NMR determination of keto-enol equilibrium constants, Experiments in Physical Chemistry, 5th Ed, McGraw-Hill, NY, 1989, pp 522-531
  • H.E. Gottlieb, V. Kotlyar & A. Nudelman: NMR chemical shifts of common laboratory solvents as trace impurities. J. Org. Chem. 62: 7512-7515, 1997.
  • J.L. Burdett & M.T. Rogers, Keto-enol tautomerism in β-dicarbonyls studied by NMR spectroscopy. I. Proton chemical shifts and equilibrium constants of pure compounds, J. Am. Chem. Soc. 86: 2105-9, 1964
  • M.T. Rogers & J.L. Burdett, Keto-enol tautomerism in β-dicarbonyls studied by NMR spectroscopy. II. Solvent effects on proton chemical shifts and on equilibrium constants, Can. J. Chem. 43: 1516-26, 1965
  • R.M. Claramunt, C. Lopez, M.D.S. Maria, D. Sanz & J. Elguero: The use of NMR spectroscopy to study tautomerism. Prog. Nucl. Magn. Reson. Spectrosc. 49: 169-206, 2006.
  • D.A. Skoog, F.J. Holler & S.R. Crouch, Principles of Instrumental Analysis, 6th ed, 2007: Chap 19: Nuclear magnetic resonance spectroscopy.
  • R.M. Silverstein & F.X. Webster, Spectrometric Identification of Organic Compounds, 6th Ed., 1998, (Baily-Howe: QD272.S6 S55 1998)
    • Chapter 4: Proton Magnetic Resonance Spectrometry (with appendices), pp. 144-216
  • R.S. Macomber, A Complete Introduction to Modern NMR Spectroscopy, 1998 (Baily-Howe: QD96.N8 M3 1998)

Lab description:

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Get free PC software to process & plot your NMR spectra off-line

Last modified February 03 2016 12:16 PM