( ! ) Warning: preg_match(): Allocation of JIT memory failed, PCRE JIT will be disabled. This is likely caused by security restrictions. Either grant PHP permission to allocate executable memory, or set pcre.jit=0 in /users/t/h/thz/www-root/wp-includes/load.php on line 1698
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
30.0005495376require_once( '/users/t/h/thz/www-root/wp-load.php ).../wp-blog-header.php:13
40.0007495848require_once( '/users/t/h/thz/www-root/wp-config.php ).../wp-load.php:50
50.0021497472require_once( '/users/t/h/thz/www-root/wp-settings.php ).../wp-config.php:91
60.0148884160wp_debug_mode( ).../wp-settings.php:80
70.0148884160wp_is_json_request( ).../load.php:487
80.0148884160wp_is_json_media_type( $media_type = '*/*' ).../load.php:1646
90.0148884568preg_match( $pattern = '/(^|\\s|,)application\\/([\\w!#\\$&-\\^\\.\\+]+\\+)?json(\\+oembed)?($|\\s|;|,)/i', $subject = '*/*' ).../load.php:1698
( ! ) Warning: Trying to access array offset on value of type bool in /users/t/h/thz/www-root/wp-content/plugins/neville-extensions/widgets/instagram/instagram-class.php on line 58
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
30.0005495376require_once( '/users/t/h/thz/www-root/wp-load.php ).../wp-blog-header.php:13
40.0007495848require_once( '/users/t/h/thz/www-root/wp-config.php ).../wp-load.php:50
50.0021497472require_once( '/users/t/h/thz/www-root/wp-settings.php ).../wp-config.php:91
60.58004573456do_action( $hook_name = 'init' ).../wp-settings.php:587
70.58004573672WP_Hook->do_action( $args = [0 => ''] ).../plugin.php:474
80.58004573672WP_Hook->apply_filters( $value = '', $args = [0 => ''] ).../class-wp-hook.php:331
90.58674578160wp_widgets_init( '' ).../class-wp-hook.php:307
100.58804611264do_action( $hook_name = 'widgets_init' ).../widgets.php:1854
110.58804612120WP_Hook->do_action( $args = [0 => ''] ).../plugin.php:474
120.58804612120WP_Hook->apply_filters( $value = '', $args = [0 => ''] ).../class-wp-hook.php:331
130.59024629416nevillex_sections( '' ).../class-wp-hook.php:307
140.59234639056require_once( '/users/t/h/thz/www-root/wp-content/plugins/neville-extensions/sections/instagram/instagram.php ).../init.php:32
150.59234639056register_widget( $widget = 'Nevillex_Section_Instagram' ).../instagram.php:361
160.59234639056WP_Widget_Factory->register( $widget = 'Nevillex_Section_Instagram' ).../widgets.php:115
170.59234639280Nevillex_Section_Instagram->__construct( ).../class-wp-widget-factory.php:61
180.59234642296Nevillex_API_Instagram::getInstance( ).../instagram.php:76
190.59234642368Nevillex_API_Instagram->__construct( ).../instagram-class.php:50
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64796685856WP_REST_Server->send_header( $key = 'Content-Type', $value = 'application/json; charset=UTF-8' ).../class-wp-rest-server.php:282
121.64796686240header( $header = 'Content-Type: application/json; charset=UTF-8' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64876686336WP_REST_Server->send_header( $key = 'X-Robots-Tag', $value = 'noindex' ).../class-wp-rest-server.php:283
121.64876686656header( $header = 'X-Robots-Tag: noindex' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64916686528WP_REST_Server->send_header( $key = 'Link', $value = '<https://www.uvm.edu/thz/index.php?rest_route=/>; rel="https://api.w.org/"' ).../class-wp-rest-server.php:287
121.64916686960header( $header = 'Link: <https://www.uvm.edu/thz/index.php?rest_route=/>; rel="https://api.w.org/"' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64926686416WP_REST_Server->send_header( $key = 'X-Content-Type-Options', $value = 'nosniff' ).../class-wp-rest-server.php:295
121.64926686736header( $header = 'X-Content-Type-Options: nosniff' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64936686480WP_REST_Server->send_header( $key = 'Access-Control-Expose-Headers', $value = 'X-WP-Total, X-WP-TotalPages, Link' ).../class-wp-rest-server.php:307
121.64946686864header( $header = 'Access-Control-Expose-Headers: X-WP-Total, X-WP-TotalPages, Link' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.64956686528WP_REST_Server->send_header( $key = 'Access-Control-Allow-Headers', $value = 'Authorization, X-WP-Nonce, Content-Disposition, Content-MD5, Content-Type' ).../class-wp-rest-server.php:331
121.64956686960header( $header = 'Access-Control-Allow-Headers: Authorization, X-WP-Nonce, Content-Disposition, Content-MD5, Content-Type' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.66826843096WP_REST_Server->send_headers( $headers = ['Link' => '<https://www.uvm.edu/thz/?page_id=61>; rel="alternate"; type=text/html', 'Allow' => 'GET'] ).../class-wp-rest-server.php:430
121.66826843096WP_REST_Server->send_header( $key = 'Link', $value = '<https://www.uvm.edu/thz/?page_id=61>; rel="alternate"; type=text/html' ).../class-wp-rest-server.php:1731
131.66826843528header( $header = 'Link: <https://www.uvm.edu/thz/?page_id=61>; rel="alternate"; type=text/html' ).../class-wp-rest-server.php:1719
( ! ) Warning: Cannot modify header information - headers already sent by (output started at /users/t/h/thz/www-root/wp-includes/load.php:1698) in /users/t/h/thz/www-root/wp-includes/rest-api/class-wp-rest-server.php on line 1719
Call Stack
#TimeMemoryFunctionLocation
10.0002493952{main}( ).../index.php:0
20.0002494384require( '/users/t/h/thz/www-root/wp-blog-header.php ).../index.php:17
31.63255624104wp( $query_vars = ??? ).../wp-blog-header.php:16
41.63255624136WP->main( $query_args = '' ).../functions.php:1310
51.63255624136WP->parse_request( $extra_query_vars = '' ).../class-wp.php:758
61.63275625192do_action_ref_array( $hook_name = 'parse_request', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp.php:396
71.63275625192WP_Hook->do_action( $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../plugin.php:522
81.63275625192WP_Hook->apply_filters( $value = '', $args = [0 => class WP { public $public_query_vars = [...]; public $private_query_vars = [...]; public $extra_query_vars = [...]; public $query_vars = [...]; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE }] ).../class-wp-hook.php:331
91.63275625840rest_api_loaded( class WP { public $public_query_vars = [0 => 'm', 1 => 'p', 2 => 'posts', 3 => 'w', 4 => 'cat', 5 => 'withcomments', 6 => 'withoutcomments', 7 => 's', 8 => 'search', 9 => 'exact', 10 => 'sentence', 11 => 'calendar', 12 => 'page', 13 => 'paged', 14 => 'more', 15 => 'tb', 16 => 'pb', 17 => 'author', 18 => 'order', 19 => 'orderby', 20 => 'year', 21 => 'monthnum', 22 => 'day', 23 => 'hour', 24 => 'minute', 25 => 'second', 26 => 'name', 27 => 'category_name', 28 => 'tag', 29 => 'feed', 30 => 'author_name', 31 => 'pagename', 32 => 'page_id', 33 => 'error', 34 => 'attachment', 35 => 'attachment_id', 36 => 'subpost', 37 => 'subpost_id', 38 => 'preview', 39 => 'robots', 40 => 'favicon', 41 => 'taxonomy', 42 => 'term', 43 => 'cpage', 44 => 'post_type', 45 => 'embed', 46 => 'post_format', 47 => 'rest_route', 48 => 'sitemap', 49 => 'sitemap-subtype', 50 => 'sitemap-stylesheet']; public $private_query_vars = [0 => 'offset', 1 => 'posts_per_page', 2 => 'posts_per_archive_page', 3 => 'showposts', 4 => 'nopaging', 5 => 'post_type', 6 => 'post_status', 7 => 'category__in', 8 => 'category__not_in', 9 => 'category__and', 10 => 'tag__in', 11 => 'tag__not_in', 12 => 'tag__and', 13 => 'tag_slug__in', 14 => 'tag_slug__and', 15 => 'tag_id', 16 => 'post_mime_type', 17 => 'perm', 18 => 'comments_per_page', 19 => 'post__in', 20 => 'post__not_in', 21 => 'post_parent', 22 => 'post_parent__in', 23 => 'post_parent__not_in', 24 => 'title', 25 => 'fields']; public $extra_query_vars = []; public $query_vars = ['rest_route' => '/wp/v2/pages/61']; public $query_string = NULL; public $request = NULL; public $matched_rule = NULL; public $matched_query = NULL; public $did_permalink = FALSE } ).../class-wp-hook.php:307
101.64786686032WP_REST_Server->serve_request( $path = '/wp/v2/pages/61' ).../rest-api.php:386
111.66826843096WP_REST_Server->send_headers( $headers = ['Link' => '<https://www.uvm.edu/thz/?page_id=61>; rel="alternate"; type=text/html', 'Allow' => 'GET'] ).../class-wp-rest-server.php:430
121.66856843096WP_REST_Server->send_header( $key = 'Allow', $value = 'GET' ).../class-wp-rest-server.php:1731
131.66856843416header( $header = 'Allow: GET' ).../class-wp-rest-server.php:1719
 {"id":61,"date":"2018-10-11T03:02:15","date_gmt":"2018-10-11T03:02:15","guid":{"rendered":"http:\/\/thz.w3.uvm.edu\/?page_id=61"},"modified":"2018-10-12T20:27:54","modified_gmt":"2018-10-12T20:27:54","slug":"porous-materials","status":"publish","type":"page","link":"https:\/\/www.uvm.edu\/thz\/?page_id=61","title":{"rendered":"Porous Materials"},"content":{"rendered":"

\"\"Porous materials are highly promising for a wide number of applications, including gas-storage and sequestration, drug delivery, and catalysis, to name a few. One of the most promising of this class of important materials are metal-organic frameworks (MOFs), which are materials that are made up of a metal cation and an organic linking molecule and often contain a large pore space in their structures. What makes MOFs special is the fact they their structures (and pores) can be readily tuned and controlled by varying either the metal cation or the organic linker, leading to a very rich set of structures and topologies. <\/p>\n

The structures that MOFs form often lead to really interesting mechanical and chemical properties, as they are often highly flexible. Since it is common for mechanical properties of organic solids to be related to terahertz vibrations, there are lots of cool MOF phenomena that can be explored using terahertz spectroscopy. <\/p>\n

In the Ruggiero Lab, we are investigating the link between the mechanical response of MOFs and their low-frequency motions, with the goal of understanding the stabilizing and destabilizing interactions within these solids. We are also very interested in probing the interactions occurring within the pores of these materials, since understanding these phenomena will allow for designing materials to better perform in advanced applications, such as drug loading and delivery, or energy storage devices. <\/p>\n

\"\"<\/a>
Vibrational levels for the hindered rotation of methyl groups in the ZIF-8 and ZIF-67 MOFs. Methyl-rotation dynamics in metal\u2013organic frameworks probed with terahertz spectroscopy<\/strong>, Chemical Communications<\/em>, 54, 5776-5779, doi:10.1039\/C8CC02650E<\/a>\u00a0(2018).<\/figcaption><\/figure>\n","protected":false},"excerpt":{"rendered":"

Porous materials are highly promising for a wide number of applications, including gas-storage and sequestration, drug delivery, and catalysis, to name a few. One of the most promising of this class of important materials are metal-organic frameworks (MOFs), which are materials that are made up of a metal cation and an organic linking molecule and […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":53,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/pages\/61"}],"collection":[{"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=61"}],"version-history":[{"count":9,"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/pages\/61\/revisions"}],"predecessor-version":[{"id":340,"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/pages\/61\/revisions\/340"}],"up":[{"embeddable":true,"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=\/wp\/v2\/pages\/53"}],"wp:attachment":[{"href":"https:\/\/www.uvm.edu\/thz\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=61"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}