Forest Ecosystem Monitoring Cooperative

Ambient Air Monitoring of Toxic Pollutants: Hazardous Air Pollutants

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Metadata Provider

  • Forest Ecosystem Monitoring Cooperative

    • Address:
      705 Spear Street
      South Burlington, Vermont 05403
      United States of America

      Phone: (802) 391-4135
      Email: femc@uvm.edu
      Website: www.uvm.edu/femc

Abstract

    The Vermont Air Quality and Climate Division (AQCD) operates three monitoring sites for ambient air toxics. These are located in Burlington, Rutland and Underhill. Samplers at the sites are operated on a 1-in-12 day (Burlington, Rutland) or 1-in-6 day sample schedule (Underhill). The Underhill site is part of the EPA National Air Toxics Trend Station (NATTS) network. The Burlington and Rutland air toxics monitoring sites are part of the VT AQCD air toxics network. The air toxic sample collection and analysis program includes volatile organic compounds (VOC) and carbonyl compounds at all sites. The NATTS - Underhill site includes sampling and analysis for PM10 metals and polyaromatic hydrocarbons (PAH) compounds.

People

  • Bennet Leon: Content Provider

  • Robert Lacaillade : Principal Investigator

  • Jenny Berschling: Content Provider

Keywords

  • air pollution, air quality, long-term monitoring, volatile organic compounds,

Organizations

  • United States Environmental Protection Agency (EPA) : lead
  • Vermont Agency of Natural Resources Department of Environmental Conservation, Division of Air Quality and Climate: partner

Geographic Coverage

  • Coordinates

    Data Table

    • Title: Hazardous Air Pollutants
    • Start Date: 1993-01-01
    • Description: Three state air monitoring sites collect ambient air samples for 96 hazardous air pollutants. These substances represent potential health risks associated with specific air toxic pollutants or hazardous air pollutants (HAP) in the ambient air.

    • Purpose: Monitor potential health risks associated with specific air toxic pollutants or hazardous air pollutants (HAP) in the ambient air. The monitoring objective for the VOC and Carbonyl sample collection and analysis is to assess long-term population exposure on a neighborhood scale, compared to applicable state standards and trend assessment. The monitoring objectives for the VOC, Carbonyl , PAH, and metals sample collection and analysis are to assess background levels on a regional scale for short and long-term trends, compared to applicable state standards and federal guidelines and assessment of contribution of transported pollutants.

    • Condensed Title:

    • Object Name: VMC.1102.2350

    • Data Type: mySQL
    • Citation: Vermont Department of Environmental Conservation Air Quality and Climate Division. 2017. Hazardous Air Pollutants. FEMC. Available online at: https://www.uvm.edu/femc/data/archive/project/ambient-air-monitoring-toxic-pollutants/dataset/hazardous-air-pollutants

    • Online Distribution: https://www.uvm.edu/femc/data/archive/project/ambient-air-monitoring-toxic-pollutants/dataset/hazardous-air-pollutants

    Attribute List

    Methods

    • Current Methods
      • Sampling HAPs
        • Started: 1993-01-01
        • Method Description: Currently, the VT AQCD measures ambient concentrations down to parts per trillion by volume (pptv) and nanogram/M3 (depending on the particular method) of 96 separate HAPs. These include volatile organic compounds (VOC) such as benzene, 1,3 butadiene; carbonyl compounds such as formaldehyde, acetaldehyde; metal compounds such as arsenic, lead; and polycyclic aromatic hydrocarbons (PAH) such naphthalene, benzo-a-pyrene. (For the complete list of Air Toxics) The VOC samples are collected using 6-liter Silco-treated stainless steel canisters which are analyzed at the VT DEC/AG lab by gas chromatography/mass spectrometry (GC/MS). The carbonyl samples are collected using a special cartridge which contains silca gel coated with dinitrophenylhydrazine (DNPH) which is extracted at the VT DEC/AG lab and analyzed by high performance liquid chromatography (HPLC). The metals samples are collected on 47 mm Teflon filters which are extracted at the VT DEC/AG lab and analyzed by inductively coupled plasma/mass spectrometry (ICP/MS). The PAH samples are collected on a 104mm quartz fiber filter combined with a polyurethane foam plug (PUF) containing XAD resin both of which are extracted at an EPA contract lab and analyzed by GC/MS.
        • Instrumentation: 6-liter Silco-treated stainless steel canisters andgas chromatographs/mass spectrometers; other specialized spectrometers


    Sampling Equipment

    • Current Equipment
      • HAP sampling
        • Started: 1993-01-01
        • Sampling Description: The permanent monitoring sites are located in Burlington, Rutland and Underhill. VOC and carbonyl samples at the Rutland and Burlington urban sites are collected every 12 days on a US EPA schedule. The Burlington site has separate collocated samplers to provide method quality assurance. At the Underhill rural site, VOC, carbonyl, metals and PAH samples are collected every 6 days on a US EPA schedule. Since 2004, the Underhill site has participated in US EPA’s National Air Toxics Trends Stations (NATTS) network designated as a rural background site.
        • Frequency: Burlington and Rutland every 1 in12 days; Underhill every 1 in 6 days

    Site Characteristics

    • Site Description: Burlington South Winooski Avenue: This site is located in a municipal parking lot of downtown Burlington, VT, located 1 km east of Lake Champlain, 1.5 km south west of McNeil Generating Station, 2 km west of I-89, and 8 km west of the Essex IBM plant. This site is designated to represent middle and neighborhood-scale. The monitoring location meets all siting requirements and criteria and has been approved by VTAQCD and EPA Region 1.

    • Minimum Altitude: 62 meters

    • Maximum Altitude: 63.1 meters

    • Site Description: Underhill at Proctor Maple Research Center: This site is located at the western slope of Mount Mansfield at the north end Underhill, VT. The site is rural in nature and located 5 km south west of the summit of Mount Mansfield, 6 km south of Route 15, and 26 km east of Burlington. This monitoring location meets all siting requirements and criteria and has been approved by VTAQCD and EPA Region 1

    • Minimum Altitude: 391 meters

    • Maximum Altitude: 392 meters

    • Site Description: Rutland: This site is located in a court house parking lot in the downtown area of Rutland, 1 km from north junction of Route 7 & Route 4, 3.5 km from south junction of Route 7 & Route 4, 4 km NW of GE plant. The site is adjacent to a postal center distribution center which serves as the parking area for USPS vehicles. This monitoring location meets all siting requirements and criteria and has been approved by VTAQCD and EPA Region 1.

    • Minimum Altitude: 164 meters

    • Maximum Altitude: 165 meters