Waterman Group Publications

It's happening: Original research data are archived here.
Follow the (data) link for publications that have original data files. Most complete data should be available for newest publications. We are working to supply data, where available, for older publications.

Please note: Original data means unprocessed data files (i.e., NMR spectra prior to a Fourier transform or image files from X-ray crystallography) supplied to allow interested investigators to reprocess our data as desired. Processed data (pictorial or tabulated) is included with publications.
Investigators who use this data are requested to cite the original article and the appropriate funding agency 

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37.Ghebreab, M. B.; Costanza, S.; Waterman, R. Selectivity Effects in Zirconium-Catalyzed Heterodehydrocoupling Reactions of Phosphines Phosphorus, Sulfur Silicon Relat. Elem., 2015, accepted.
36.Weismann, J.; Waterman, R.; Gessner, V. H. Metal ligand Cooperativity in a Methandiide Derived Iridium Carbene Complex, 2015, submitted.
35.Bange, C. A.; Ghebreab, M. B.; Ficks, A.; Mucha, N. T.; Higham, L.; Waterman, R. Zirconium-Catalyzed Intermolecular Hydrophosphination Using a Chiral, Air-Stable Primary Phosphine, 2015, accepted. (data)
34.McGrew, G. I.; Khatri, P.A.; Geiger, W. E.;  Kemp, R. A.; Waterman, R. Unexpected Formal Insertion of CO2 into the C–Si Bonds of a Zinc Compound Chem. Commun., 2015, 51, 15804–15807.
33. Pagano, J. K.; Dorhout, J. M.; Czerwinski, K. R.; Waterman, R; Kiplinger, J. L. Phenylsilane as a Safe, Versatile Alternative to Hydrogen for the Synthesis of Actinide Hydrides Chem. Commun., 2015, accepted.
32.Erickson, K. A.; Stelmach, J. P. W.; Mucha, N. T.; Waterman, R. Zirconium Catalyzed Amine-Borane Dehydrocoupling and Transfer Hydrogenation Organometallics, 2015, 34, 4693–4699. Part of the Hillhouse Memorial Issue.
31.Rawat, N.; Lamarche, C. J.; Tokumoto, T.; Wetherby, A. J.; Waterman, R.; Headrick, R. L.; McGill, S. A.; Furis, M. Magnetic Circular Dichroism (MCD) Study of Exchange Interaction in Polycrystalline Thin Films of Copper Octabutoxy Phthalocyanine, 2015, submitted.
30.Mucha, N. T.; Waterman, R.   Iridium Pincer Catalysts for Silane Dehydrocoupling: Ligand Effects on Selectivity and Activity Organometallics, 2015, 34, 3865–3872. (data)
29.Rawat, N.; Pan, Z.; Manning, L. W.; Cour, I.; Headrick, R. L.; Waterman, R.; Woll, A. R.; Furis, M. I. Spatially, Temporally and Polarization-Resolved Photoluminescence Exploration of Excitons in Crystalline Phthalocyanine Thin Films J. Phys. Chem. Lett. 2015, 6, 1834-1840.
28.Baker, L. A.; Chakraverty, D.; Columbus, L.; Feig, A. L.; Jenks, W. S.; Pilarz, M.; Stains, M.; Waterman, R.; Wesemann, J. L. Cottrell Scholars Collaborative New Faculty Workshop: Professional Development for New Chemistry Faculty J. Chem. Educ. 2014, 91, 1874-1881.

27.Pagano, J. K.; Stelmach, J. P. W.; Waterman, R. Cobalt-Catalyzed Ammonia Borane Dehydrocoupling and Transfer Hydrogenation under Aerobic Conditions Dalton Trans. 2015, 44, 12074-12077. (data)
26.Erickson, K. A., Dixon, L. S. H.; Wright, D. S., Waterman, R. Exploration of Tin-Catalyzed Dehydrocoupling: Catalyst Effects and Observation of Tin-Catalyzed: Hydrophosphination Inorg. Chim. Acta 2014, accepted. (Protagonist in Chemistry: T. Don Tilley special issue)
25.Ghebreab, M. B.; Bange, C. A.; Waterman, R. Intermolecular Zirconium-Catalyzed Hydrophosphination of Alkenes and Dienes with Primary Phosphines J. Am. Chem. Soc. 2014, 136, 9240–9243.
24.Erickson, K. A., Wright, D. S., Waterman, R. Dehydrocoupling of Amine Boranes via Tin(IV) and Tin(II) Catalysts J. Organomet. Chem., 2014, 751, 541–545. Part of the 50th anniversary special issue. (data)
23. Waterman, R. sigma-Bond Metathesis: A 30-Year Retrospective Organometallics, 2013, 32, 7249-7263.
22. Barry, B. M.; Stein, B. W.; Larsen, C. A.; Wirtz, M. N.; Geiger, W. E.; Waterman, R.; Kemp, R. A. Metal Complexes (M = Zn, Sn, and Pb) of 2-Phosphinobenzenethiolates: Insights into Ligand Folding and Hemilability Inorg. Chem., 2013, 52, 9875–9884. 
21. Maddox, A. F.; Davidson, J. J.; Shalumova, T.; Tanski, J. M.; Waterman, R. Zirconium-Mediated Synthesis of Arsaalkene Compounds from Arsines and Isocyanides Inorg. Chem., 2013, 52, 7811-7816.
20. Waterman, R. Mechanisms of Metal-Catalyzed Dehydrocoupling Reactions Chem. Soc. Rev. 2013, 42, 5629-5641.
19. Roering, A. J.; Elrod, L. T.; Pagano, J. K.; Guillot, S. L.; Chan, S. M.; Tanski, J. M.; Waterman, R. A General, Zirconium-Mediated Synthesis of Phosphaalkenes with Liberation of Phosphaformamides Dalton Trans. 2013, 42, 1159–1167.
18. Elrod, L. T.; Boxwala, H.; Haq, H.; Zhao, A. W.; Waterman, R. As–As Bond Formation via Reductive Elimination from a Zirconocene Bis(Dimesitylarsenide) Compound Organometallics 2012, 31, 5304-5307. (data)
17. Kuhune, M. E.; Waterman, R. rac-Methoxycoronaridine Hydrochloride Acta Cryst. E. 2012, 68(4), o1041. (data)
16. Vaughan, B. A.; Wetherby A. E.; Waterman, R. Bis(p-tolyl-(2Z,4E)-4-(p-tolylimino)pent-2-en-2-yl)amino)zinc(II) Acta Cryst. E. 2012, 68(3), m343. (data)
15. Vaughan, B. A.; Arsenault, E. A.; Chan, S. M.; Waterman, R. Synthesis and Characterization of Zinc Complexes and Testing for Phosphine Dehydrocoupling Reactivity J. Organomet. Chem. 2012, 4327-4331.
14. Waterman, R. Dehydrogenative Bond-Forming Catalysis Involving Phosphines: Updated Through 2010 Curr. Org. Chem. 201216, 1313-1331.
13. Maddox, A. F.; Erickson, K. A.; Tanski, J. M.; Waterman, R. C–N Bond Formation via Ligand-Induced Nucleophilicity at a Coordinated Triamidoamine Ligand Chem. Commun. 2011, 11769-11771.
12. Ghebreab, M. B.; Newsham, D. K.; Waterman, R. Differences in the Stability of Zirconium(IV) Complexes Related to Catalytic Phosphine Dehydrocoupling Reactions Dalton Trans. 2011, 40, 7683–7685.
11. Leshinski, S. E.; Shalumova, T.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Insertion Reactions Involving a Triamidoamine-Supported Zirconium Complex Dalton Trans., 2010, 39, 9073-9078. 
10. Roering, A. J.; Leshinski, S. E.; Chan, S. M.; Shalumova, T.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Insertion Reactions and Catalytic Hydrophosphination by Triamidoamine-Supported Zirconium Complexes Organometallics, 2010, 29, 2557-2565.
9. Ghebreab, M. B.; Shalumova, T.; Tanski, J. M.; Waterman, R. Triamidoamine-Supported Zirconium Complexes in the Catalytic Dehydrocoupling of 1,2-Bisphosphinobenzene and –Ethane Polyhedron  - Young Investigator Special Issue 2010, 29, 42-45.
8. Roering, A. J.; Maddox, A. F.; Elrod, L. T.; Chan, S. M.; Ghebreab, M. B.; Donovan, K. L.; Davidson, J. J.; Hughes, R. P.; Shalumova, T.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. General Preparation of (N3N)ZrX (N3N = N(CH2CH2NSiMe3)33–) Complexes from a Hydride Surrogate Organometallics 2009, 28, 573-581.
7. Waterman, R. Metal-Phosphido and -Phosphinidene Complexes in P-E Bond-Forming Reactions Dalton Trans. 2009, 18-26.
6. Waterman, R. Dehydrogenative Bond-Forming Catalysis Involving Phosphines Curr. Org. Chem. 2008, 12, 1322-1339.
5. Roering, A. J.; Davidson, J. J.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Mechanistic Variety in Zirconium-Catalyzed Bond-Forming Reaction of Arsines Dalton Trans. 2008, 4488-4498.
4. MacMillan, S. N.; Tanski, J. M.; Waterman, R. {N,N-Bis[2-(trimethylsilylamino)ethyl]-N-(trimethylsilyl)ethane- 1,2-diaminato(3–)-K4N}methylzirconium(IV) Acta Cryst. E. 2008, E64, m477.

MacMillan, S. N.; Tanski, J. M.; Waterman, R. Insertion of Benzylisocyanide into a Zr-P bond and Rearrangement. Atom-Economical Synthesis of a Phosphaalkene Chem. Commun. 2007, 4172-4174.

Roering, A. J.; MacMillan, S. N.; Tanski, J. M.; Waterman, R. Zirconium-Catalyzed Heterodehydrocoupling of Primary Phosphines with Silanes and Germanes Inorg. Chem. 2007, 46, 6855-6857.

Waterman, R. Selective Dehydrocoupling of Phosphines by Triamidoamine Zirconium Catalysts Organometallics  2007, 26, 2492-2494.